JMSSJ On-line, Vol. 52 (2004) No. 6, pp. 325-327
Detection of Metal Oxides by MALDI/TOF MS
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    Kozo MATSUMOTO, *a) Aritaka MATSUNAMI, b) Hiroyuki OYAMA, b) Miho TANAKA, c) and Kuniyuki KITAGAWA b)

    *a) Department of Applied Chemistry, Graduate School of Engineering, Nagoya University (Furo-cho, Chikusa-ku, Nagoya 464-8603, Japan) b) EcoTopia Science Institute, Nagoya University (Furo-cho, Chikusa-ku, Nagoya 464-8603, Japan) c) Tokyo University of Marine Science and Technology (Kounan, Minato-ku, Tokyo 108-8477, Japan)

We have applied MALDI/TOF MS to the analysis of metal oxides by using chelating agents as matrices. The identification of metals is performed without any complicated pretreatment. Moreover, the oxidation numbers of the metals are determinable by using suitable chelating reagents. This simple method is successfully applied to the analysis of metal elements in natural crystal stone (Pyrite, FeS2).

Key words: MALDI/TOF MS, Copper, Iron, Pyrite

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